Excitonic Properties of Chemically Synthesized 2D Organic–Inorganic Hybrid Perovskite Nanosheets

2D organic–inorganic hybrid perovskites (OIHPs) represent a unique class of materials with a natural quantum‐well structure and quasi‐2D electronic properties. Here, a versatile direct solution‐based synthesis of mono‐ and few‐layer OIHP nanosheets and a systematic study of their electronic structure as a function of the number of monolayers by photoluminescence and absorption spectroscopy are reported. The monolayers of various OIHPs are found to exhibit high electronic quality as evidenced by high quantum yield and negligible Stokes shift. It is shown that the ground exciton peak blueshifts by ≈40 meV when the layer thickness reduces from bulk to monolayer. It is also shown that the exciton binding energy remains effectively unchanged for (C₆H₅(CH₂)₂NH₃)₂PbI₄ with the number of layers. Similar trends are observed for (C₄H₉NH₃)₂PbI₄ in contrast to the previous report. Further, the photoluminescence lifetime is found to decrease with the number of monolayers, indicating the dominant role of surface trap states in nonradiative recombination of the electron–hole pairs.     

Assessment of toxic content in Balanites aegyptiaca seed cake and use of enzymatic-catalysed biodiesel in diesel engine

The present study deals with the estimation of toxic phorbol esters in Balanites aegyptiaca seed cake and to evaluate the performance and combustion characteristics of different blends of biodiesel in a diesel engine. The seeds were manually collected from arid regions of Rajasthan, India and the oil extracted from the powdered kernel with Solvent extraction process. The extracted oil processed by enzymatic catalytic reactions are carried out at optimum operating conditions such as the molar ratio of 8:1 (methanol:oil), reaction temperature at 40°C for 4?h reaction time and xylanase 1% based on oil weight. The total conversion rate of extracted oil to methyl ester by enzymatic reactions yields up to 98.3%. The toxic content of seed cake was determined by high-performance liquid chromatography (HPLC, Shimadzu). The performance and combustion parameters such as BP, BTE and CP decreased, whereas BSFC and DP increased with biodiesel blends.     

Catalytic combustion of methane over a highly active and stable NiO/CeO2 catalyst

In the last decades, many reports dealing with technology for the catalytic combustion of methane (CH₄) have been published. Recently, attention has increasingly focused on the synthesis and catalytic activity of nickel oxides. In this paper, a NiO/CeO₂ catalyst with high catalytic performance in methane combustion was synthesized via a facile impregnation method, and its catalytic activity, stability, and water-resistance during CH₄ combustion were investigated. X-ray diffraction, low-temperature N₂ adsorption, thermogravimetric analysis, Fourier transform infrared spectroscopy, hydrogen temperature programmed reduction, methane temperature programmed surface reaction, Raman spectroscopy, electron paramagnetic resonance, and transmission electron microscope characterization of the catalyst were conducted to determine the origin of its high catalytic activity and stability in detail. The incorporation of NiO was found to enhance the concentration of oxygen vacancies, as well as the activity and amount of surface oxygen. As a result, the mobility of bulk oxygen in CeO₂ was increased. The presence of CeO₂ prevented the aggregation of NiO, enhanced reduction by NiO, and provided more oxygen species for the combustion of CH₄. The results of a kinetics study indicated that the reaction order was about 1.07 for CH₄ and about 0.10 for O₂ over the NiO/CeO₂ catalyst.     

Extending social responsibility to small and medium-sized suppliers in supply chains: A fuzzy-set qualitative comparative analysis

Buying firms’ sales and reputation will be greatly damaged by any non-responsible behaviors on the part of suppliers, especially when those suppliers, like small and medium-sized enterprises (SMEs), have restricted resources and capabilities. To eradicate these risks, a growing number of buying firms have introduced socially responsible supplier development (SRSD). SRSD, including monitoring and evaluating suppliers, can provide them with incentives and assistance. Based on configuration theory and contingency theory, fuzzy-set qualitative comparative analysis (fsQCA) is adopted in this study to examine how SRSD practices adopted by buying firms, supply chain partnership, and market turbulence affect the corporate social responsibility (CSR) performance of their SME suppliers. We find that, as core factors, supplier monitoring, supplier assistance, and supply chain partnership can work together with peripheral conditions to achieve superior CSR performance. In addition, even at different levels of market turbulence, superior CSR performance can be realized through different causal configurations.     

Novel Gemini Cationic Surfactants: Thermodynamic,Antimicrobial Susceptibility,and Corrosion Inhibition Behavior against Acidithiobacillus ferrooxidans

The Egyptian oil and gas industry is suffering from severe metal corrosion problems, particularly microbial-induced corrosion. There is limited knowledge on the corrosion inhibition of carbon steels in the presence of an acidophilic, iron-oxidizing bacterial species Acidithiobacillus ferrooxidans. Therefore, in this study, novel Gemini cationic surfactants, in three forms depending on variation in alkyl chains of 8, 12, and 16 carbon atoms named FHPAO, FHPAD, and FHPAH, respectively, were synthesized and characterized by Fourier transform infrared and nuclear magnetic resonance spectroscopy. The surface parameters and the thermodynamic of the synthesized surfactants were evaluated at three different temperatures, 20, 40, and 60 °C. The synthesized Gemini cationic surfactants were tested as broad-spectrum antimicrobial, antibacterial and anticandida agents. They evaluated as biocides and corrosion inhibitors against Acidithiobacillus ferrooxidans. FHPAD showed higher adsorption ability at the solution interface and higher affinity to construct micelles than FHPAO and FHPAH. Both adsorption and micellization processes were hydrophobic and temperature dependent. FHPAO, FHPAD and FHPAH exhibited wide-spectrum antimicrobial activities, and the highest activity and the lowest minimum bactericidal/fungicidal inhibitory concentrations were attributed to FHPAD. Furthermore, synthesized FHPAD demonstrated the highest metal corrosion inhibition efficiency of 95.5% at 5 mM in comparison to 87.5% and 81.7% for FHPAO and FHPAH, respectively. In conclusion, this study provides novel synthesized cationic surfactants with many applications in the oil and gas industry, such as broad-spectrum antimicrobial, biocides, and corrosion inhibitors for acidophilic, iron-oxidizing bacterial species Acidithiobacillus ferrooxidans.     

Hydraulics and bridges: A French case study of monitoring of a bridge affected by scour

Bridges are one of the oldest types of civil engineering structures and the interaction between the transport and hydrographic networks represents a significant issue in a country such as France. Recently, various cases highlight the importance and vulnerability of civil transport works in relation to their environmental hazards, e.g. floods, and therefore the need to develop integrated observation tools and warning systems in the aim both of optimizing the management system and of increasing the knowledge on real scour processes. This paper reports on the “field approach” task of a research project aiming at improving continuous monitoring in order to follow the evolution of the scour processes of a given bridge or abutment. The first step has been to identify a pilot site, representative of scour vulnerability. After a report of the scour parameters to be monitored, the benchmark study and the choice of monitoring devices available on the market are detailed. Instrumentation, sensor adaptability, limitations (actual measurement ranges, ergonomics, energy supply limits …) and in situ implementation are then presented and discussed. Finally, preliminary measurements, post-treatments and interpretation are detailed.     

北洺河铁矿全尾砂胶结充填治理塌陷区的可行性研究

北洺河铁矿为践行“绿水青山就是金山银山”的绿色发展理念,探索利用选厂尾矿治理地表塌陷区方案。通过对北洺河铁矿塌陷区稳定性分析以及对全尾砂膏体制备、输送、胶结充填技术可行性试验研究,并结合经济估算、环境和社会效益等综合分析,认为全尾砂胶结充填治理塌陷区的方案可行。     

Seeing sweet and choosing sour: Compensatory effects of typeface on consumers’ choice behavior

The present research included two field studies investigating, firstly, the effects of round and angular typefaces on taste expectations and, secondly, how such expectations may have downstream effects on naturalistic consumer choice. A taste experiment conducted at a science festival asked participants (N = 125) to rate the expected and actual sweetness and sourness of beer served from plastic cups labelled with either angular or round typeface. Effects of typeface were found on both taste expectations and perceived taste, but in opposite directions; participants rated the expected sourness of a beer as higher in the round (vs. angular) typeface condition, whereas they rated perceived sourness as lower in the round compared to the angular typeface condition. A follow-up field study conducted at a beer bar tested whether different typefaces on a beer board would affect actual beer choices. Data consisted of beer transactions (N = 1,952) and included the monetary amount, and the specific style, and size of beer purchased. The results showed that average transaction amount was lower in the round (vs. angular) typeface condition, and that customers purchased more sour beer options in this condition. These findings support a crossmodal compensation account, and suggest that round typefaces could increase choices of contrasting sour products. Hence, marketers may want to consider how typefaces can either enhance or diminish certain tastes.     

谈如何在预可研阶段做好工程造价控制

工程造价控制是现代工程建设、管理的核心工作之一,要求在现有基础上不断予以完善。本文以预可研阶段工程造价控制作为分析对象,论述该阶段工程造价控制的关键点,再以此为基础,分析预可研阶段的工程造价控制思路,最后从递进关联的角度,就工程造价控制的后续方法进行论述,给出构建精细化作业模式、加强数据挖掘和复用、重点项目的拆分等内容,服务后续工作。